Bromine and iodine for selective partial oxidation of propane and methane
نویسندگان
چکیده
منابع مشابه
Selective CH functionalization of methane, ethane, and propane by a perfluoroarene iodine(III) complex.
Direct partial oxidation of methane, ethane, and propane to their respective trifluoroacetate esters is achieved by a homogeneous hypervalent iodine(III) complex in non-superacidic (trifluoroacetic acid) solvent. The reaction is highly selective for ester formation (>99%). In the case of ethane, greater than 0.5 M EtTFA can be achieved. Preliminary kinetic analysis and density functional calcul...
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ژورنال
عنوان ژورنال: Applied Catalysis A: General
سال: 2019
ISSN: 0926-860X
DOI: 10.1016/j.apcata.2019.05.003